RV and PES University majority of the companies visit both with same package. A bit better in PESU so you get more opportunity in PESU but number of students is more in PES University (almost double CS students) so competition is higher compared to RV. So getting into tier 1 companies (CTC of 8Lpa+) is tougher in PESU. Percentage of people getting Tier 1 is higher in RV due to less strength but number of people getting to Tier 1 is bit higher in PESU. Almost 80% of companies visiting RV and PESU go to BMS. It has the least competition compared to RV and PESU and opportunities are bit less. MSRIT follows after BMS.
If you think you can stay ahead of others in competition PESU is better. Else RVCE is better as chances of getting into Tier 1 company is bit higher.